Characterization and Controlled Release Formulation of Agrochemical Herbicides Based on Zinc-Layered Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite

Research Article

Characterization and Controlled Release Formulation of Agrochemical Herbicides Based on Zinc-Layered Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite

Norhayati Hashim, Zuhailimuna Muda, Shahidah Abdul Hamid, Illyas Md Isa, Azlan Kamari, Azmi Mohamed,Mohd Zobir Hussein, Sazelli Ab. Ghani

Corresponding Author : Norhayati Hashim,

Department of Chemistry, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjong Malim, Perak, Malaysia.

Email ID : norhayati.hashim@fsmt.upsi.edu.my

Received : 2014-06-23 Accepted : 2014-07-21 Published : 2014-07-21

Abstract : Nanocomposite of zinc layered hydroxide-3-(4-methoxyphenyl) propionate (ZLH-MPP) were prepared by intercalation of 3-(4-methoxyphenyl) propionic acid (MPP) into the interlamellae of zinc layered hydroxide (ZLH) by using direct reaction of an aqueous suspension of zinc oxide with MPP solution via one step method. Power x-ray diffraction patterns showed the result of successful intercalation of ZLH-MPP nanocomposite at 27.3 Ã… at a low angle of reflection. The result was also supported by FTIR spectra and elemental analysis of the nanocomposite. On the basis of EDX and TGA-DTG results, the chemical formula of ZLH-MPP nanocomposite was Zn(OH)1.47(CH3OC6H4CH2CH2COO-)0.53.0.87H2O). The controlled release of MPP from interlayer of ZLH-MPP nanocomposite showed that phosphate medium yielded the highest percentage release compared to sulphate and chloride medium. The release of MPP was found to be in controlled manner governed by pseudo-second order for phosphate medium and first order for sulphate and chloride medium.

Keywords : Nanocomposite, Zinc layered hydroxide 3-(4-methoxyphenyl) propionic acid, Controlled release

Citation : Norhayati Hashim, et al (2014) Characterization and Controlled Release Formulation of Agrochemical Herbicides Based on Zinc-Layered Hydroxide-3-(4-Methoxyphenyl) Propionate Nanocomposite. j. of Physical and Chemical Sciences.V1I4.03. DOI : 10.5281/zenodo.890953

Copyright : © 2014 Norhayati Hashim. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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